论文
Fe,N-Codoped Graphdiyne Displaying Efficient Oxygen Reduction Reaction Activity
发表年度: 2019
期: 1
卷: 12
页: 173-178
摘要: On account of the high-cost of platinum, researchers are working to develop a new catalyst that is cheaper and has a catalytic effect equivalent to platinum. Herein, owing to the unique acetylenic bonds in graphdiyne, iron, nitrogen co-doped graphdiyne (Fe-N-GDY) is a promising nonprecious metal catalyst, which has been developed with just a small amount of iron precursor with the plan to substitute it for Pt-based catalysts. The as-synthesized Fe-N-GDY composited catalyst shows excellent catalytic performance with the onset potential of 0.94 V versus reversible hydrogen electrode and limited current density of 5.4 mA cm(-2). Moreover, it shows excellent resistance to methanol poisoning and stability in both acidic and alkaline electrolytes, which makes potentially applicable in the oxygen reduction reaction field.
刊物名称: CHEMSUSCHEM
影响因子: 7.804