| 发表年度： | 2019 |
|---|---|
| 期： | 19 |
| 卷： | 6 |
| 页： | 3401-3407 |
| 摘要： | A metal-free, acid-free and chemoselective N-dealkylation-N-nitrosation or C-nitration of N-alkyl anilines has been developed. tert-Butyl nitrite (TBN) efficiently promotes the synthesis of N-nitrosoanilines, nitroanilines and N-nitroso-nitroanilines with good to excellent yields and chemoselectivities. The selective reduction of N-nitrosoanilines and N-nitroso-nitroanilines was smoothly achieved, affording phenylhydrazine, 2-nitroaniline and 1,2-benzenediamine derivatives. |
| 刊物名称： | ORGANIC CHEMISTRY FRONTIERS |
| 影响因子： | 5.076 |
