论文
Highly Efficient and Stable Atomically Dispersed Cu Catalyst for Azide-Alkyne Cycloaddition Reaction
第一作者: Ren, P (Ren, Peng); Li, QL (Li, Qinglin); Song, T (Song, Tao); Wang, ZZ (Wang, Zhaozhan); Motokura, K (Motokura, Ken); Yang, Y (Yang, Yong);
联系作者: Ren, P (Ren, Peng); Li, QL (Li, Qinglin); Song, T (Song, Tao); Wang, ZZ (Wang, Zhaozhan); Motokura, K (Motokura, Ken); Yang, Y (Yang, Yong);
发表年度: 2021
页: -
摘要: In this study, we report a highly stable and efficient single-atom Cu dispersed on N-doped porous carbon as a superior catalyst for azide-alkyne cycloaddition reaction. A broad set of 1,4-disubstituted 1,2,3-triazoles was synthesized in high to excellent yields with good tolerance of various functional groups in a cost-effective, environment-friendly manner. Parallel studies show that the single-atom Cu with unique coordination structure exhibits superior catalytic activity to the metallic Cu nanoparticles analogue. Remarkably, the single-atom Cu catalyst demonstrates robust stability and can be reused several times without variations in activity and regioselectivity.
刊物名称: CHEMCATCHEM
影响因子: 4.495
全文链接: https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202100831