| 第一作者: | Ren, P (Ren, Peng); Li, QL (Li, Qinglin); Song, T (Song, Tao); Wang, ZZ (Wang, Zhaozhan); Motokura, K (Motokura, Ken); Yang, Y (Yang, Yong); |
|---|---|
| 联系作者: | Ren, P (Ren, Peng); Li, QL (Li, Qinglin); Song, T (Song, Tao); Wang, ZZ (Wang, Zhaozhan); Motokura, K (Motokura, Ken); Yang, Y (Yang, Yong); |
| 发表年度: | 2021 |
| 页: | - |
| 摘要: | In this study, we report a highly stable and efficient single-atom Cu dispersed on N-doped porous carbon as a superior catalyst for azide-alkyne cycloaddition reaction. A broad set of 1,4-disubstituted 1,2,3-triazoles was synthesized in high to excellent yields with good tolerance of various functional groups in a cost-effective, environment-friendly manner. Parallel studies show that the single-atom Cu with unique coordination structure exhibits superior catalytic activity to the metallic Cu nanoparticles analogue. Remarkably, the single-atom Cu catalyst demonstrates robust stability and can be reused several times without variations in activity and regioselectivity. |
| 刊物名称: | CHEMCATCHEM |
| 影响因子: | 4.495 |
| 全文链接: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.202100831 |