| 第一作者： | Wang, Z (Wang, Zhong); Li, SJ (Li, Shuangju); Zhang, CH (Zhang, Chuanhui); Wang, D (Wang, Da); Li, XB (Li, Xuebing); |
|---|---|
| 联系作者： | Wang, Z (Wang, Zhong); Li, SJ (Li, Shuangju); Zhang, CH (Zhang, Chuanhui); Wang, D (Wang, Da); Li, XB (Li, Xuebing); |
| 发表年度： | 2021 |
| 期： | 2 |
| 卷： | 25 |
| 页： | 103-113 |
| 摘要： | The selective catalytic oxidation of ammonia (SCO) to N-2 seems to be the most promising technology to remove NH3. Compared with electrocatalytic and photocatalytic ammonia oxidation technology, the thermal catalytic oxidation ammonia technology was sufficient to support large-scale commercial and industrial applications. The NH3-SCO reaction was strongly obeyed the reaction routes of imide, hydrazinium-type and iSCR mechanism. Further, in situ (electron paramagnetic resonance) EPR spectroscopy combined with DFT calculation could provide a foundation for the design and construction of highly efficient ammonia oxidation catalyst. Finally, important ideas for NH3-SCO should be given the 100% N-2 selectivity and higher NH3 conversion at lowest temperature. If Ag single-atoms were inserted in the tunnels of zeolites or MOF to result in single Ag atoms anchored at the tunnel, this single-atom Ag particles exhibited super NH3 conversion, N-2 selectivity and hydrothermal durability at low temperatures. |
| 刊物名称： | CATALYSIS SURVEYS FROM ASIA |
| 影响因子： | 2.25 |
| 全文链接： | https://link.springer.com/article/10.1007/s10563-020-09320-6 |
