| 第一作者： | Zheng, K (Zheng, Ke); Shi, S (Shi, Song); Xin, HC (Xin, Hongchuan); Gao, J (Gao, Jin); An, ZJ (An, Zengjian); |
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| 联系作者： | Zheng, K (Zheng, Ke); Shi, S (Shi, Song); Xin, HC (Xin, Hongchuan); Gao, J (Gao, Jin); An, ZJ (An, Zengjian); |
| 发表年度： | 2021 |
| 卷： | 150 |
| 页： | - |
| 摘要： | A method for the selective activation of C-H bond of phenol in ortho-position into C-OH bond was developed at room temperature over Cu2+ ions in a two-phase system using marginally water-soluble polar alcohols, acetonitrile and water as solvents and hydrogen peroxide as an oxidant. In a homogeneous system, phenol was oxidized to produce catechol and 1,4-hydroquinone with a ratio of 0.77:1.0. The addition of alcohols resulted in a two-phase system, and the ratio of catechol and 1,4-hydroquinone was increased to 4.4:1.0. Compared with a homogeneous system, the selectivity for catechol increased for over 5 times in the two-phase counterpart. This offers an effective hydroxylation method for producing catechol from phenol. |
| 刊物名称： | CATALYSIS COMMUNICATIONS |
| 影响因子： | 3.674 |
| 全文链接： | https://www.sciencedirect.com/science/article/pii/S1566736720303538?via%3Dihub |
