| 第一作者： | Hu, TM (Hu, Tianmiao); Liang, WY (Liang, Wenyuan); Xia, XL (Xia, Xiaoliang); Peng, H (Peng, Hui); Jiang, HQ (Jiang, Heqing); |
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| 联系作者： | Hu, TM (Hu, Tianmiao); Liang, WY (Liang, Wenyuan); Xia, XL (Xia, Xiaoliang); Peng, H (Peng, Hui); Jiang, HQ (Jiang, Heqing); |
| 发表年度： | 2021 |
| 卷： | 364 |
| 页： | 125-131 |
| 摘要： | Oxygen transport membrane reactors were often utilized to integrate air separation with catalytic oxidation of methane for producing syngas. In this work, we employed Fe-based BaCe0.5Fe0.5O3-delta (BCF5050) membrane with satisfied oxygen permeability to simultaneously produce pure nitrogen and syngas via coupling air separation with oxy-CO2 reforming of methane. By co-feeding CH4 and CO2 in reaction side of membrane, oxygen in air side can efficiently permeate to the other side of membrane. After introducing a porous layer and Ni/Al2O3 on methane side, it was found that removal rate of oxygen from air can be significantly enhanced, which finally resulted in a higher nitrogen purity. Nitrogen with a purity over 99.3 % was constantly produced at a rate of ca. 3.6 cm(3) min(-1) at the exit of air side. Meanwhile, CH4 and CO2 conversion of over 92 %, CO and H-2 selectivity of above 95 % were also achieved on the other side of membrane during 140 h test period. |
| 刊物名称： | CATALYSIS TODAY |
| 影响因子： | 4.888 |
| 全文链接： | https://www.sciencedirect.com/science/article/pii/S0920586120304338?via%3Dihub |
