论文
Pure cellulose lithium-ion battery separator with tunable pore size and improved working stability by cellulose nanofibrils
第一作者: Lv, D (Lv, Dong); Chai, JC (Chai, Jingchao); Wang, P (Wang, Peng); Zhu, LY (Zhu, Lingyu); Liu, C (Liu, Chao); Nie, SX (Nie, Shuangxi); Li, B (Li, Bin); Cui, GL (Cui, Guanglei);
联系作者: Lv, D (Lv, Dong); Chai, JC (Chai, Jingchao); Wang, P (Wang, Peng); Zhu, LY (Zhu, Lingyu); Liu, C (Liu, Chao); Nie, SX (Nie, Shuangxi); Li, B (Li, Bin); Cui, GL (Cui, Guanglei);
发表年度: 2021
卷: 251
页: -
摘要: Separator is a vital component of lithium-ion batteries (LIBs) due to its important roles in the safety and electrochemical performance of the batteries. Herein, we reported a cellulose nanofibrils (CNFs) reinforced pure cellulose paper (CCP) as a LIBs separator fabricated by a facile filtration process. The nanosized CNFs played crucial roles as a tuner to optimize the pore size of the as-prepared CCP, and also as a reinforcer to improve the mechanical strength of the resultant CCP. Results showed that the tensile strength of the CCP with 20 wt.% CNFs was 227 % higher compared to the commercial cellulose separator. In addition, the lithium cobalt oxide/lithium metal battery assembled with CCP separator displayed better cycle performance and working stability (capacity retention ratio of 91 % after 100 cycles) compared to the batteries with cellulose separator (52 %) and poly-propylene separator (84 %) owing to the multiple synergies between CCP separator and electrolytes.
刊物名称: CARBOHYDRATE POLYMERS
影响因子: 6.044
全文链接: https://www.sciencedirect.com/science/article/pii/S0144861720311486?via%3Dihub