| 第一作者： | Lv, CD (Lv, Chengdong); Xu, GQ (Xu, Guangqiang); Yang, RL (Yang, Rulin); Zhou, L (Zhou, Li); Wang, QG (Wang, Qinggang); |
|---|---|
| 联系作者： | Lv, CD (Lv, Chengdong); Xu, GQ (Xu, Guangqiang); Yang, RL (Yang, Rulin); Zhou, L (Zhou, Li); Wang, QG (Wang, Qinggang); |
| 发表年度： | 2021 |
| 页： | - |
| 摘要： | Chiral phosphoric acid (CPA) catalyzed asymmetric kinetic resolution polymerization (AKRP) of 6-methyl-epsilon-caprolactone (6-MeCL) has been developed to synthesize stereogradient polycaprolactones. When using (R)-CPA as the catalyst, (R)-6-MeCL monomers were preferentially consumed, which was determined by chiral Hplc analysis and kinetic experiments. The AKRP process delivered polycaprolactones (PCLs) with high chain-end fidelity, controlled molecular weights and narrow molar mass dispersity. Moreover, the thermal properties, viscoelasticity and degradation characteristics of the resulting PCLs were also investigated. |
| 刊物名称： | POLYMER CHEMISTRY |
| 影响因子： | 4.76 |
| 全文链接： | https://pubs.rsc.org/en/content/articlelanding/2021/PY/D1PY00366F |
